低碳经济下绿色证券市场资源配置研究

随着经济高速发展,高耗能、高污染的问题日益严重,通过绿色证券资源配置可以达到低碳、环保的目的。该文分析了绿色证券市场的资源配置模式,并对中国绿色证券市场的现状进行了分析;最后从上市条件、制度和立法等方面对提高绿色证券市场资源配置效率提出了具体的对策。     

碳纳米管的酸化处理对碳纳米管/聚氨酯复合材料微观结构及性能的影响

对多壁碳纳米管进行酸化处理,并采用原位聚合法制备了碳纳米管/聚氨酯复合材料。利用X射线光电子能谱分析(XPS)、电子扫描显微镜(SEM)、动态力学分析(DMA)研究了碳纳米管酸化与否对复合材料性能的影响。结果表明,碳纳米管经酸化处理后产生了羧基,碳纳米管的原位加入使得复合材料的储存模量和玻璃化转变温度都有所提高,而且经过酸化的碳纳米管对聚氨酯材料的改性要比未酸化碳纳米管对聚氨酯材料的改性效果更为显著。     

Earthworms increase soil microbial biomass carrying capacity and nitrogen retention in northern hardwood forests

Earthworms have been shown to produce contrasting effects on soil carbon (C) and nitrogen (N) pools and dynamics. We measured soil C and N pools and processes and traced the flow of ¹³C and ¹⁵N from sugar maple (Acer saccharum Marsh.) litter into soil microbial biomass and respirable C and mineralizable and inorganic N pools in mature northern hardwood forest plots with variable earthworm communities. Previous studies have shown that plots dominated by either Lumbricus rubellus or Lumbricus terrestris have markedly lower total soil C than uncolonized plots. Here we show that total soil N pools in earthworm colonized plots were reduced much less than C, but significantly so in plots dominated by contain L. rubellus. Pools of microbial biomass C and N were higher in earthworm-colonized (especially those dominated by L. rubellus) plots and more ¹³C and ¹⁵N were recovered in microbial biomass and less was recovered in mineralizable and inorganic N pools in these plots. These plots also had lower rates of potential net N mineralization and nitrification than uncolonized reference plots. These results suggest that earthworm stimulation of microbial biomass and activity underlie depletion of soil C and retention and maintenance of soil N pools, at least in northern hardwood forests. Earthworms increase the carrying capacity of soil for microbial biomass and facilitate the flow of N from litter into stable soil organic matter. However, declines in soil C and C:N ratio may increase the potential for hydrologic and gaseous losses in earthworm-colonized sites under changing environmental conditions.     

Contribution of Different Organs to Grain Filling in Durum Wheat under Mediterranean Conditions I. Contribution of Post‐Anthesis Photosynthesis and Remobilization

Under Mediterranean conditions, drought affects cereals production principally through a limitation of grain filling. In this study, the respective role of post‐anthesis photosynthesis and carbon remobilization and the contribution of flag leaf, stem, chaff and awns to grain filling were evaluated under Mediterranean conditions in durum wheat (Triticum turgidum var. durum) cultivars. For the purpose, we examined the effects of shading and excision of different parts of the plant and compared carbon isotope discrimination (Δ) in dry matter of flag leaf, stem, chaff, awns and grain at maturity and in sap of stem, flag leaf, chaff and awns, this last measurement providing information on photosynthesis during a short period preceding sampling. Source–sink manipulations and isotopic imprints of different organs on final isotope composition of the grain confirmed the high contribution of both carbons assimilated by ears and remobilized from stems to grain filling, and the relatively low contribution of leaves to grain filling. Grain Δ was highly and significantly associated with grain yield across treatments, suggesting the utilization of this trait as an indicator of source–sink manipulations effects on grain yield. Chaff and awns Δ were better correlated with grain Δ than stem and leaf Δ, indicating that chaff were more involved in grain filling than other organs. Moreover, in chaff, sap Δ was highly significantly correlated with dry matter Δ. These results suggest the use of Δ for a rapid and non‐destructive estimation of the variation in the contribution of different organs to grain filling.     

Shifts in microbial diversity through land use intensity as drivers of carbon mineralization in soil

Land use practices alter the biomass and structure of soil microbial communities. However, the impact of land management intensity on soil microbial diversity (i.e. richness and evenness) and consequences for functioning is still poorly understood. Here, we addressed this question by coupling molecular characterization of microbial diversity with measurements of carbon (C) mineralization in soils obtained from three locations across Europe, each representing a gradient of land management intensity under different soil and environmental conditions. Bacterial and fungal diversity were characterized by high throughput sequencing of ribosomal genes. Carbon cycling activities (i.e., mineralization of autochthonous soil organic matter, mineralization of allochthonous plant residues) were measured by quantifying ¹²C- and ¹³C-CO₂ release after soils had been amended, or not, with ¹³C-labelled wheat residues. Variation partitioning analysis was used to rank biological and physicochemical soil parameters according to their relative contribution to these activities. Across all three locations, microbial diversity was greatest at intermediate levels of land use intensity, indicating that optimal management of soil microbial diversity might not be achieved under the least intensive agriculture. Microbial richness was the best predictor of the C-cycling activities, with bacterial and fungal richness explaining 32.2 and 17% of the intensity of autochthonous soil organic matter mineralization; and fungal richness explaining 77% of the intensity of wheat residues mineralization. Altogether, our results provide evidence that there is scope for improvement in soil management to enhance microbial biodiversity and optimize C transformations mediated by microbial communities in soil.     

Energy use and greenhouse gas emissions from turf management of two Swedish golf courses

Turf management on golf courses entails frequent maintenance activities, such as mowing, irrigation and fertilisation, and relies on purchased inputs for optimal performance and aesthetic quality. Using life cycle assessment (LCA) methodology, this study evaluated energy use and greenhouse gas (GHG) emissions from management of two Swedish golf courses, divided into green, tee, fairway and rough, and identified options for improved management. Energy use and GHG emissions per unit area were highest for greens, followed by tees, fairways and roughs. However, when considering the entire golf course, both energy use and GHG emissions were mainly related to fairway and rough maintenance due to their larger area. Emissions of GHG for the two golf courses were 1.0 and 1.6 Mg CO₂e ha⁻¹ year⁻¹ as an area-weighted average, while the energy use was 14 and 19 GJ ha⁻¹ year⁻¹. Mowing was the most energy-consuming activity, contributing 21 and 27% of the primary energy use for the two golf courses. In addition, irrigation and manufacturing of mineral fertiliser and machinery resulted in considerable energy use. Mowing and emissions associated with fertilisation (manufacturing of N fertiliser and soil emissions of N₂O occurring after application) contributed most to GHG emissions. Including the estimated mean annual soil C sequestration rate for fairway and rough in the assessment considerably reduced the carbon footprint for fairway and turned the rough into a sink for GHG. Emissions of N₂O from decomposition of grass clippings may be a potential hotspot for GHG emissions, but the high spatial and temporal variability of values reported in the literature makes it difficult to estimate these emissions for specific management regimes. Lowering the application rate of N mineral fertiliser, particularly on fairways, should be a high priority for golf courses trying to reduce their carbon footprint. However, measures must be adapted to the prevailing conditions at the specific golf course and the requirements set by golfers.     

Evaluation of direct and indirect phosphorus limitation of methanogenic pathways in a calcareous subtropical wetland soil

The effect of phosphorus (P) and carbon (C) on methanogenesis was investigated in a low-P (130 mg P kg⁻¹ soil) wetland within Everglades National Park. Soil was amended with C substrates (acetate, formate, butyrate, and glucose) with or without P, and CO₂ and CH₄ production was monitored. Production of CH₄ increased with P addition although no effect on CO₂ was observed. Methane production was stimulated by all C substrates except for butyrate. No effect of C on CO₂ production was observed except for stimulation following glucose addition. Production of CH₄ following formate addition was not affected by P, suggesting hydrogenotrophic methanogens may be substrate, not P, limited. Addition of P to all other C substrates heightened CH₄ production and lowered the CO₂–C:CH₄–C ratio relative to the corresponding C only treatment, suggesting that P may have limited acetoclastic methanogens and fermentation.     

Comparative economic performance and carbon footprint of two farming models for producing Atlantic salmon (Salmo salar): Land-based closed containment system in freshwater and open net pen in seawater

Ocean net pen production of Atlantic salmon is approaching 2 million metric tons (MT) annually and has proven to be cost- and energy-efficient. Recently, with technology improvements, freshwater aquaculture of Atlantic salmon from eggs to harvestable size of 4–5 kg in land-based closed containment (LBCC) water recirculating aquaculture systems (RAS) has been demonstrated as a viable production technology. Land-based, closed containment water recirculating aquaculture systems technology offers the ability to fully control the rearing environment and provides flexibility in locating a production facility close to the market and on sites where cost of land and power are competitive. This flexibility offers distinct advantages over Atlantic salmon produced in open net pen systems, which is dependent on access to suitable coastal waters and a relatively long transport distance to supply the US market. Consequently, in this paper we present an analysis of the investment needed, the production cost, the profitability and the carbon footprint of producing 3300 MT of head-on gutted (HOG) Atlantic salmon from eggs to US market (wholesale) using two different production systems—LBCC-RAS technology and open net pen (ONP) technology using enterprise budget analysis and carbon footprint with the LCA method. In our analysis we compare the traditional open net pen production system in Norway and a model freshwater LBCC-RAS facility in the US. The model ONP is small compared to the most ONP systems in Norway, but the LBCC-RAS is large compared to any existing LBCC-RAS for Atlantic salmon. The results need to be interpreted with this in mind. Results of the financial analysis indicate that the total production costs for two systems are relatively similar, with LBCC-RAS only 10% higher than the ONP system on a head-on gutted basis (5.60 US$/kg versus 5.08 US$/kg, respectively). Without interest and depreciation, the two production systems have an almost equal operating cost (4.30 US$/kg for ONP versus 4.37 US$/kg for LBCC-RAS). Capital costs of the two systems are not similar for the same 3300 MT of head-on gutted salmon. The capital cost of the LBCC-RAS model system is approximately 54,000,000 US$ and the capital cost of the ONP system is approximately 30,000,000 US$, a difference of 80%. However, the LBCC-RAS model system selling salmon at a 30% price premium is comparatively as profitable as the ONP model system (profit margin of 18% versus 24%, respectively), even though its 15-year net present value is negative and its return on investment is lower than ONP system (9% versus 18%, respectively). The results of the carbon footprint analysis confirmed that production of feed is the dominating climate aspect for both production methods, but also showed that energy source and transport methods are important. It was shown that fresh salmon produced in LBCC-RAS systems close to a US market that use an average US electricity mix have a much lower carbon footprint than fresh salmon produced in Norway in ONP systems shipped to the same market by airfreight, 7.41 versus 15.22 kg CO₂eq/kg salmon HOG, respectively. When comparing the carbon footprint of production-only, the LBCC-RAS-produced salmon has a carbon footprint that is double that of the ONP-produced salmon, 7.01 versus 3.39 kg CO₂eq/kg salmon live-weight, respectively.     

Environmental impacts from herbicide tolerant canola production in Western Canada

The commercial production of herbicide tolerant (HT) canola began in Western Canada in 1997. With more than a decade of use, the actual farm-level environmental impact of HT canola can be evaluated. This article reports on a spring 2007 survey of nearly 600 canola farmers in the three prairie provinces of Western Canada. Producers were asked about their crop production experiences for 2005 and 2006 and expected crop planting for 2007. A reduction in the total number of chemical applications over the 3-year period was reported, resulting in a decrease of herbicide active ingredient being applied to farmland in Western Canada of nearly 1.3 million kg annually. Fewer tillage passes over the survey period were reported, improving moisture conservation, decreasing soil erosion and contributing to carbon sequestration in annual cropland. An estimated 1 million tonnes of carbon is either sequestered or no longer released under land management facilitated by HT canola production, as compared to 1995. The value of this carbon off-set is estimated to be C$5 million. Comparisons with similar studies and against non-adoption of HT canola can guide future decisions about HT canola adoption.     

Sensitivity to information upscaling of agro-ecological assessments: Application to soil organic carbon management

Upscaling of agro-ecological indicators applied in regional analyses is sensitive to scale issues of the input data. This study develops a methodology to quantify this sensitivity for an indicator of soil organic carbon (SOC) dynamics at the farming system level. A reference case consists of seven fully described farms in northern Italy. Both upscaling in complexity by substituting measured input with estimated input and upscaling in space by extending the methods to farms not included in the reference case are addressed. The indicator increased with 3-107% at four farms after substituting measured management input with that estimated by an expert, whereas it remained unchanged or decreased at the other three farms. Taking the modal value from a cluster of pedological input did not lead to additional uncertainty in most cases, and only slightly increased it in others. We evaluated spatial upscaling by including 733 farms divided in 18 clusters that were described with less information as compared to the reference farms. Within each cluster, we observed relevant variability of the indicator (coefficients of variation of 12-43%), as a consequence of the heterogeneity of farms comprised in each cluster. In each cluster we calculated the indicator for one virtual farm, defined by using modal values for basic farm inputs. In this case the indicator was highly correlated (R² = 0.98) with the average of the values obtained using measured basic farm inputs. We conclude that upscaling in complexity and space introduces uncertainty in the values of the indicator compared to the reference case. The extent of such differences depends on the variability of the systems under analysis and on indicator sensitivity.